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Has Cassini found a universal driver for prebiotic chemistry at Titan?

26 July 2017

An important type of molecule that helps produce complex organic material has been detected within Titan鈥檚 hazy upper atmosphere by a 香港六合彩中特网-led team as part of the international Cassini-Huygens mission.

Has Cassini found a universal driver for prebiotic chemistry at Titan?

In the study, published in Astrophysical Journal Letters, scientists identified negatively charged molecules called 鈥榗arbon chain anions鈥 in the atmosphere of Titan, Saturn鈥檚 largest moon. These linear molecules are understood to be building blocks towards more complex molecules, and may have acted as the basis for the earliest forms of life on Earth.听

The team say the discovery of the negatively charged carbon chain anions is surprising because they are highly reactive and should not last long in Titan鈥檚 atmosphere before combining with other materials. Their discovery there is completely reshaping current understanding of the hazy moon鈥檚 atmosphere.

The detections were made using Cassini鈥檚 plasma spectrometer, called CAPS, as Cassini flew through Titan鈥檚 upper atmosphere, 950鈥1300 km above the surface.

Interestingly, the data show that the carbon chains become depleted closer to the moon, while precursors to larger aerosol molecules undergo rapid growth. This suggests a close relationship between the two, with the carbon chains 鈥榮eeding鈥 the larger molecules that are thought to fall down to, and deposit on, the surface.

鈥淲e have made the first unambiguous identification of carbon chain anions in a planet-like atmosphere, which we believe are a vital stepping-stone in the production line of growing bigger, and more complex organic molecules, such as the moon鈥檚 large haze particles,鈥 said Ravi Desai, study lead author and PhD student at 香港六合彩中特网.

鈥淭his is a known process in the interstellar medium 鈥 the large molecular clouds from which stars themselves form 鈥 but now we鈥檝e seen it in a completely different environment, meaning it could represent a universal process for producing complex organic molecules. The question is, could it also be happening at other nitrogen-methane atmospheres like at Pluto or Triton, or at exoplanets with similar properties?鈥

Titan boasts a thick nitrogen and methane atmosphere with some of the most complex chemistry seen in the Solar System. It is even thought to mimic the atmosphere of early Earth, before the build-up of oxygen. As such, Titan can be seen as a planet-scale laboratory that can be studied to understand the chemical reactions that may have led to life on Earth, and that could be occurring on planets around other stars.

鈥淭he prospect of a universal pathway towards the ingredients for life has implications for what we should look for in the search for life in the Universe,鈥 said co-author Professor Andrew Coates, also from 香港六合彩中特网 and co-investigator of CAPS. 鈥淭itan presents a local example of exciting and exotic chemistry, from which we have much to learn.鈥

Titan's atmospheric chemistry
In Titan鈥檚 upper atmosphere, nitrogen and methane are exposed to energy from sunlight and energetic particles in Saturn鈥檚 magnetosphere. These energy sources drive reactions involving nitrogen, hydrogen and carbon, which lead to more complicated prebiotic compounds.

These large molecules drift down towards the lower atmosphere, forming a thick haze of organic aerosols, and are thought to eventually reach the surface. But the process by which simple molecules in the upper atmosphere are transformed into the complex organic haze at lower altitudes is complicated and difficult to determine. This discovery adds vital information that will help scientists understand the chemical process.

鈥淭hese inspiring results from Cassini show the importance of tracing the journey from small to large chemical species in order to understand how complex organic molecules are produced in an early Earth-like atmosphere,鈥 added Dr Nicolas Altobelli, ESA鈥檚 Cassini project scientist. 鈥淲hile we haven鈥檛 detected life itself, finding complex organics not just at Titan, but also in comets and throughout the interstellar medium, we are certainly coming close to finding its precursors.鈥

Cassini鈥檚 13-year odyssey in the Saturnian system will soon draw to a close, but future missions, such as the international James Webb Space Telescope and ESA鈥檚 exoplanet mission Plato are equipped to look for this process not only in our own Solar System but elsewhere. Advanced ground-based facilities such as ALMA could also enable follow-up observations of this process at work in Titan鈥檚 atmosphere, from Earth.